Preprint
In press
2022
[141]
Muta, R.; Torigoe, T.; Kuninobu, Y.*
3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic Activation
Org. Lett. 2022, 24, 8218-8222 (DOI: 10.1021/acs.orglett.2c03327).
ChemRxiv 2022 (DOI: 10.26434/chemrxiv-2022-5lw1l).
Muta, R.; Torigoe, T.; Kuninobu, Y.*
3-Position-Selective C–H Trifluoromethylation of Pyridine Rings Based on Nucleophilic Activation
Org. Lett. 2022, 24, 8218-8222 (DOI: 10.1021/acs.orglett.2c03327).
ChemRxiv 2022 (DOI: 10.26434/chemrxiv-2022-5lw1l).
[140]
Mori, T.; Sekine, K.; Kawashima, K.; Mori, T.; Kuninobu, Y.*
Near-Infrared and Dual Emissions of Diphenylamino Group-Substituted Malachite Green Derivatives
Eur. J. Org. Chem. 2022, 2022, e202200873 (DOI: 10.1002/ejoc.202200873).
Mori, T.; Sekine, K.; Kawashima, K.; Mori, T.; Kuninobu, Y.*
Near-Infrared and Dual Emissions of Diphenylamino Group-Substituted Malachite Green Derivatives
Eur. J. Org. Chem. 2022, 2022, e202200873 (DOI: 10.1002/ejoc.202200873).
[139]
Shiozuka, A.; Sekine, K.*; Toki, T.; Kawashima, K.; Mori, T.*; Kuninobu, Y.*
Photoinduced Divergent Deaminative Borylation and Hydrodeamination of Primary Aromatic Amines
Org. Lett. 2022, 24, 4281-4285 (DOI: 10.1021/acs.orglett.2c01663).
Shiozuka, A.; Sekine, K.*; Toki, T.; Kawashima, K.; Mori, T.*; Kuninobu, Y.*
Photoinduced Divergent Deaminative Borylation and Hydrodeamination of Primary Aromatic Amines
Org. Lett. 2022, 24, 4281-4285 (DOI: 10.1021/acs.orglett.2c01663).
[138]
Kawazu, R.; Torigoe, T.*; Kuninobu, Y.*
Iridium-catalyzed C(sp3)–H Borylation Using Silyl-Bipyridine Pincer Ligands
Angew. Chem. Int. Ed. 2022, 61, e202202327 (DOI: 10.1002/anie.202202327).
[Hot Paper]
Kawazu, R.; Torigoe, T.*; Kuninobu, Y.*
Iridium-catalyzed C(sp3)–H Borylation Using Silyl-Bipyridine Pincer Ligands
Angew. Chem. Int. Ed. 2022, 61, e202202327 (DOI: 10.1002/anie.202202327).
[Hot Paper]
[137]
Kuninobu, Y.*
Creation of Transition Metal Catalysts with Substrate Recognition Moiety and Development of Regioselective and Substrate Specific Reactions
J. Synth. Org. Chem. Jpn. 2022, 80, 421-430 (DOI: 10.5059/yukigoseikyokaishi.80.421).
[Accounts, Invited]
Kuninobu, Y.*
Creation of Transition Metal Catalysts with Substrate Recognition Moiety and Development of Regioselective and Substrate Specific Reactions
J. Synth. Org. Chem. Jpn. 2022, 80, 421-430 (DOI: 10.5059/yukigoseikyokaishi.80.421).
[Accounts, Invited]
[136]
Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*
Photoinduced Organic Reactions by Employing Pyrene Catalysts
Synthesis 2022, 54, 2330-2339 (DOI: 10.1055/a-1739-4793).
[Review, Invited]
Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*
Photoinduced Organic Reactions by Employing Pyrene Catalysts
Synthesis 2022, 54, 2330-2339 (DOI: 10.1055/a-1739-4793).
[Review, Invited]
[135]
Zeng, J.; Torigoe, T.*; Kuninobu, Y.*
Control of Site-Selectivity in Hydrogen Atom Transfer by Electrostatic Interaction: Proximal-Selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Using a Decatungstate Photocatalyst
ACS Catal. 2022, 12, 3058-3062 (DOI: 10.1021/acscatal.2c00278).
Zeng, J.; Torigoe, T.*; Kuninobu, Y.*
Control of Site-Selectivity in Hydrogen Atom Transfer by Electrostatic Interaction: Proximal-Selective C(sp3)–H Alkylation of 2-Methylanilinium Salts Using a Decatungstate Photocatalyst
ACS Catal. 2022, 12, 3058-3062 (DOI: 10.1021/acscatal.2c00278).
[134]
Li, H.-L.*; Yang, D.; Jing, H.-Q.; Antilla, J.*; Kuninobu, Y.*
Palladium-Catalyzed Enantioselective C(sp3)–H Arylation of 2-Propyl Azaaryls Enabled by Amino Acid Ligand
Org. Lett. 2022, 24, 1286-1291 (DOI: 10.1021/acs.orglett.1c04215).
Li, H.-L.*; Yang, D.; Jing, H.-Q.; Antilla, J.*; Kuninobu, Y.*
Palladium-Catalyzed Enantioselective C(sp3)–H Arylation of 2-Propyl Azaaryls Enabled by Amino Acid Ligand
Org. Lett. 2022, 24, 1286-1291 (DOI: 10.1021/acs.orglett.1c04215).
[133]
Jiang, Z.; Sekine, K.; Kuninobu, Y.*
Synthesis of Fluorenes and Their Related Compounds from Biaryls and Meldrum’s Acid Derivatives
Chem. Commun. 2022, 58, 843-846 (DOI: 10.1039/D1CC06212C).
Jiang, Z.; Sekine, K.; Kuninobu, Y.*
Synthesis of Fluorenes and Their Related Compounds from Biaryls and Meldrum’s Acid Derivatives
Chem. Commun. 2022, 58, 843-846 (DOI: 10.1039/D1CC06212C).
2021
[132]
Dong, Y.; Sekine, K.; Kuninobu, Y.*
Facile Synthesis of Tribenzosilepins from Terphenyls and Dihydrosilanes by Electrophilic Double Silylation
Chem. Commun. 2021, 57, 7007-7010 (DOI: 10.1039/D1CC02326H).
Dong, Y.; Sekine, K.; Kuninobu, Y.*
Facile Synthesis of Tribenzosilepins from Terphenyls and Dihydrosilanes by Electrophilic Double Silylation
Chem. Commun. 2021, 57, 7007-7010 (DOI: 10.1039/D1CC02326H).
[131]
Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*
Photoinduced Deaminative Borylation of Unactivated Aromatic Amines Enhanced by CO2
Org. Lett. 2021, 23, 4774-4778 (DOI: 10.1021/acs.orglett.1c01503). [One of the most viewed articles in July 2021.]
ChemRxiv 2021 (DOI: 10.26434/chemrxiv.14397191.v1).
Shiozuka, A.; Sekine, K.*; Kuninobu, Y.*
Photoinduced Deaminative Borylation of Unactivated Aromatic Amines Enhanced by CO2
Org. Lett. 2021, 23, 4774-4778 (DOI: 10.1021/acs.orglett.1c01503). [One of the most viewed articles in July 2021.]
ChemRxiv 2021 (DOI: 10.26434/chemrxiv.14397191.v1).
[130]
Lu, X.; Kawazu, R.; Song, J.; Yoshigoe, Y.; Torigoe, T.; Kuninobu, Y.*
Regioselective C-H Trifluoromethylation of Aromatic Compounds by Inclusion in Cyclodextrins
Org. Lett. 2021, 23, 4327-4331 (DOI: 10.1021/acs.orglett.1c01259).
ChemRxiv 2021 (DOI: 10.26434/chemrxiv.14173655.v1).
Lu, X.; Kawazu, R.; Song, J.; Yoshigoe, Y.; Torigoe, T.; Kuninobu, Y.*
Regioselective C-H Trifluoromethylation of Aromatic Compounds by Inclusion in Cyclodextrins
Org. Lett. 2021, 23, 4327-4331 (DOI: 10.1021/acs.orglett.1c01259).
ChemRxiv 2021 (DOI: 10.26434/chemrxiv.14173655.v1).
[129]
Sneh, K.; Torigoe, T.; Kuninobu, Y.*
Manganese/Bipyridine-catalyzed Non-directed C(sp3)-H Bromination Using NBS and TMSN3
Beilstein J. Org. Chem. 2021, 17, 885-890 (DOI: 10.3762/bjoc.17.74).
[Invited, Open Access]
Sneh, K.; Torigoe, T.; Kuninobu, Y.*
Manganese/Bipyridine-catalyzed Non-directed C(sp3)-H Bromination Using NBS and TMSN3
Beilstein J. Org. Chem. 2021, 17, 885-890 (DOI: 10.3762/bjoc.17.74).
[Invited, Open Access]
[128]
Li, Y.; Miyamoto, S.; Torigoe, T.; Kuninobu, Y.*
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT
Org. Biomol. Chem. 2021, 19, 3124-3127 (DOI: 10.1039/D1OB00326G).
Li, Y.; Miyamoto, S.; Torigoe, T.; Kuninobu, Y.*
Regioselective C(sp3)–H Alkylation of Fructopyranose Derivative by 1,6 HAT
Org. Biomol. Chem. 2021, 19, 3124-3127 (DOI: 10.1039/D1OB00326G).
[127]
Wang, J.; Torigoe, T.; Kuninobu, Y.*
Urea-accelerated Iridium-catalyzed 2-Position-selective C-H Borylation of Indole Derivatives
Chem. Lett. 2021, 50, 808-811 (DOI:10.1246/cl.200939).
[Open Access]
Wang, J.; Torigoe, T.; Kuninobu, Y.*
Urea-accelerated Iridium-catalyzed 2-Position-selective C-H Borylation of Indole Derivatives
Chem. Lett. 2021, 50, 808-811 (DOI:10.1246/cl.200939).
[Open Access]
[126]
Kuninobu, Y.*; Torigoe, T.
Regioselective C-H Trifluoromethylation of Heteroaromatic Compounds
Bull. Chem. Soc. Jpn. 2021, 94, 532-541 (DOI:10.1246/bcsj.20200302).
[Review, Invited, Open Access]
Kuninobu, Y.*; Torigoe, T.
Regioselective C-H Trifluoromethylation of Heteroaromatic Compounds
Bull. Chem. Soc. Jpn. 2021, 94, 532-541 (DOI:10.1246/bcsj.20200302).
[Review, Invited, Open Access]
2020
[125]
Yang, Y.; Cao, F.; Yao, L.; Shi, T.; Tang, B.*; Kuninobu, Y.*; Wang, Z.*
C-N and C-O Bond Formation in Copper-Catalyzed/Mediated sp3 C-H Activation: Mechanistic Studies from Experimental and Computational Aspects
J. Org. Chem. 2020, 85, 9713-9726 (DOI: 10.1021/acs.joc.0c01038).
Yang, Y.; Cao, F.; Yao, L.; Shi, T.; Tang, B.*; Kuninobu, Y.*; Wang, Z.*
C-N and C-O Bond Formation in Copper-Catalyzed/Mediated sp3 C-H Activation: Mechanistic Studies from Experimental and Computational Aspects
J. Org. Chem. 2020, 85, 9713-9726 (DOI: 10.1021/acs.joc.0c01038).
[124]
Li, H.-L.: Kuninobu, Y.*; Antilla, J. C.*
Palladium-catalyzed Secondary C(sp3)-H Arylation of 2-Alkylpyridines
Adv. Synth. Catal. 2020, 362, 2637-2641 (DOI: 10.1002/adsc.202000306).
Li, H.-L.: Kuninobu, Y.*; Antilla, J. C.*
Palladium-catalyzed Secondary C(sp3)-H Arylation of 2-Alkylpyridines
Adv. Synth. Catal. 2020, 362, 2637-2641 (DOI: 10.1002/adsc.202000306).
[123]
Kuninobu, Y.*; Torigoe, T.
Resent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions
Org. Biomol. Chem. 2020, 18, 4126-4134 (DOI: 10.1039/D0OB00703J).
[Review, Invited].
Kuninobu, Y.*; Torigoe, T.
Resent Progress on Transition Metal-catalysed Regioselective C–H Transformations Based on Noncovalent Interactions
Org. Biomol. Chem. 2020, 18, 4126-4134 (DOI: 10.1039/D0OB00703J).
[Review, Invited].
[122]
Zeng, J.; Naito, M.; Torigoe, T.; Yamanaka, M.*; Kuninobu, Y.*
Iridium-Catalyzed ortho-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand
Org. Lett. 2020, 22, 3485-3489 (DOI: 10.1021/acs.orglett.0c00946).
Zeng, J.; Naito, M.; Torigoe, T.; Yamanaka, M.*; Kuninobu, Y.*
Iridium-Catalyzed ortho-C–H Borylation of Thioanisole Derivatives Using Bipyridine-Type Ligand
Org. Lett. 2020, 22, 3485-3489 (DOI: 10.1021/acs.orglett.0c00946).
[121]
Furuta, S.; Mori, T.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.*
Synthesis, Structures and Photophysical Properties of Hexacoordinated Organosilicon Compounds with 2-(2-Pyridyl)phenyl Groups
Org. Biomol. Chem. 2020, 18, 3239-3242 (DOI: 10.1039/D0OB00484G).
Furuta, S.; Mori, T.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.*
Synthesis, Structures and Photophysical Properties of Hexacoordinated Organosilicon Compounds with 2-(2-Pyridyl)phenyl Groups
Org. Biomol. Chem. 2020, 18, 3239-3242 (DOI: 10.1039/D0OB00484G).
[120]
Dong, Y.; Sakai, M.; Fuji, K.; Sekine, K.; Kuninobu, Y.*
Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction
Beilstein J. Org. Chem. 2020, 16, 409-414 (DOI: 10.3762/bjoc.16.39).
[Invited, Open Access]
Dong, Y.; Sakai, M.; Fuji, K.; Sekine, K.; Kuninobu, Y.*
Synthesis of six-membered silacycles by borane-catalyzed double sila-Friedel–Crafts reaction
Beilstein J. Org. Chem. 2020, 16, 409-414 (DOI: 10.3762/bjoc.16.39).
[Invited, Open Access]
[119]
Miwa, N.; Tanaka, C.; Ishida, S.; Hirata, G.; Song, J.; Torigoe, T.; Kuninobu, Y.*; Nishikata, T.*
Copper-Catalyzed Tertiary Alkylative Cyanation for the Synthesis of Cyanated Peptide Building Blocks
J. Am. Chem. Soc. 2020, 142, 1692-1697 (DOI: 10.1021/jacs.9b113497).
Miwa, N.; Tanaka, C.; Ishida, S.; Hirata, G.; Song, J.; Torigoe, T.; Kuninobu, Y.*; Nishikata, T.*
Copper-Catalyzed Tertiary Alkylative Cyanation for the Synthesis of Cyanated Peptide Building Blocks
J. Am. Chem. Soc. 2020, 142, 1692-1697 (DOI: 10.1021/jacs.9b113497).
[R012]
Kuninobu, Y.; Sueki, S.; Kaplaneris, N.; Ackermann, L.
Manganese Catalysis
Catalysis with Earth-abundant Elements 2020, 139-230 (DOI: 10.1039/9781788012775).
Kuninobu, Y.; Sueki, S.; Kaplaneris, N.; Ackermann, L.
Manganese Catalysis
Catalysis with Earth-abundant Elements 2020, 139-230 (DOI: 10.1039/9781788012775).
[R011]
國信 洋一郎
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 ～新しい位置選択性制御法の創出：非共有結合性相互作用の利用～
Organometallic News 2020, 40-45.
國信 洋一郎
有機機能性分子合成を志向した新規炭素－水素結合変換反応の開発 ～新しい位置選択性制御法の創出：非共有結合性相互作用の利用～
Organometallic News 2020, 40-45.
[R010]
鳥越 尊、國信 洋一郎
有機溶媒がいらない!? －固体状態での高効率クロスカップリング反応
化学 2020, 75, 64-65. （2020年6月号、最新のトピックス、化学同人）
鳥越 尊、國信 洋一郎
有機溶媒がいらない!? －固体状態での高効率クロスカップリング反応
化学 2020, 75, 64-65. （2020年6月号、最新のトピックス、化学同人）
2019
[118]
Tahara, A.; Kitahara, I.; Sakata, D.; Kuninobu, Y.; Nagashima, H.*
Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties
J. Org. Chem. 2019, 84, 15236-15254 (DOI: 10.1021/acs.joc.9b02267).
Tahara, A.; Kitahara, I.; Sakata, D.; Kuninobu, Y.; Nagashima, H.*
Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties
J. Org. Chem. 2019, 84, 15236-15254 (DOI: 10.1021/acs.joc.9b02267).
[117]
Dong, Y.; Takata, Y.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.*
Lewis acid-catalyzed synthesis of silafluorene derivatives from biphenyls and dihydrosilanes via a double sila-Friedel–Crafts reaction
Chem. Commun. 2019, 55, 13303-13306 (DOI: 10.1039/c9cc07692a).
Dong, Y.; Takata, Y.; Yoshigoe, Y.; Sekine, K.; Kuninobu, Y.*
Lewis acid-catalyzed synthesis of silafluorene derivatives from biphenyls and dihydrosilanes via a double sila-Friedel–Crafts reaction
Chem. Commun. 2019, 55, 13303-13306 (DOI: 10.1039/c9cc07692a).
[116]
Mori, T.; Yoshigoe, Y.; Kuninobu, Y.*
Control of Multicolor and White Emissions by Tuning Equilibrium Between Fluorophores, Lewis Acids, and Their Complexes Using Polymers
Angew. Chem. Int. Ed. 2019, 58, 14457-14461 (DOI: 10.1002/anie.201903408).
Mori, T.; Yoshigoe, Y.; Kuninobu, Y.*
Control of Multicolor and White Emissions by Tuning Equilibrium Between Fluorophores, Lewis Acids, and Their Complexes Using Polymers
Angew. Chem. Int. Ed. 2019, 58, 14457-14461 (DOI: 10.1002/anie.201903408).
[115]
Muta, R.; Torigoe, T.; Kuninobu, Y.*
2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds
Org. Lett. 2019, 21, 4289-4292 (DOI: 10.1021/acs.orglett.9b01474).
Muta, R.; Torigoe, T.; Kuninobu, Y.*
2-Position-Selective Trifluoromethylthiolation of Six-Membered Heteroaromatic Compounds
Org. Lett. 2019, 21, 4289-4292 (DOI: 10.1021/acs.orglett.9b01474).
[114]
Togo, T.; Sohma, Y.; Kuninobu, Y.; Kanai, M.*
Palladium-Catalyzed C–H Heteroarylation of 2,5-Disubstituted Imidazoles
Chem. Pharm. Bull. 2019, 67, 196-198 (DOI: 10.1248/cpb.c18-00586).
[Invited]
Togo, T.; Sohma, Y.; Kuninobu, Y.; Kanai, M.*
Palladium-Catalyzed C–H Heteroarylation of 2,5-Disubstituted Imidazoles
Chem. Pharm. Bull. 2019, 67, 196-198 (DOI: 10.1248/cpb.c18-00586).
[Invited]
[113]
Wang, J.; Torigoe, T.; Kuninobu, Y.*
Hydrogen-Bond-Controlled Formal Meta-Selective C-H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds
Org. Lett. 2019, 21, 1342-1346 (DOI: 10.1021/acs.orglett.9b00030).
Wang, J.; Torigoe, T.; Kuninobu, Y.*
Hydrogen-Bond-Controlled Formal Meta-Selective C-H Transformations and Regioselective Synthesis of Multisubstituted Aromatic Compounds
Org. Lett. 2019, 21, 1342-1346 (DOI: 10.1021/acs.orglett.9b00030).
[112]
Lu, X.; Yoshigoe, Y.; Ida, H.; Nishi, M.; Kanai, M.; Kuninobu, Y.*
Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities
ACS Catal. 2019, 9, 1705-1709 (DOI: 10.1021/acscatal.8b05005).
Lu, X.; Yoshigoe, Y.; Ida, H.; Nishi, M.; Kanai, M.; Kuninobu, Y.*
Hydrogen Bond-Accelerated meta-Selective C-H Borylation of Aromatic Compounds and Expression of Functional Group and Substrate Specificities
ACS Catal. 2019, 9, 1705-1709 (DOI: 10.1021/acscatal.8b05005).
2018
[111]
Yamakawa, T.; Yoshigoe, Y.; Wang, Z.; Kanai, M.; Kuninobu, Y.*
Preparation of Solid-state Luminescent Materials by Complexation between π-Conjugated Molecules and Activators
Chem. Lett. 2018, 47, 1391-1394 (DOI: 10.1246/cl.180735).
Yamakawa, T.; Yoshigoe, Y.; Wang, Z.; Kanai, M.; Kuninobu, Y.*
Preparation of Solid-state Luminescent Materials by Complexation between π-Conjugated Molecules and Activators
Chem. Lett. 2018, 47, 1391-1394 (DOI: 10.1246/cl.180735).
[110]
Kuninobu, Y.*
Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules
Synlett 2018, 29, 2093-2107 (DOI: 10.1055/s-0037-1610531).
[Personal Account, Invited]
Kuninobu, Y.*
Development of Novel C-H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules
Synlett 2018, 29, 2093-2107 (DOI: 10.1055/s-0037-1610531).
[Personal Account, Invited]
[109]
Ni, J.; Taniguchi, A.; Ozawa, S.; Hori, Y.; Kuninobu, Y.; Saito, T.; Saido, T. C.; Tomita, T.; Sohma, Y.*; Kanai, M.*
Near-Infrared Photoactivatable Oxygenation Catalysts of Amyloid Peptide
Chem 2018, 4, 807-820 (DOI: 10.1016/j.chempr.2018.02.008).
Ni, J.; Taniguchi, A.; Ozawa, S.; Hori, Y.; Kuninobu, Y.; Saito, T.; Saido, T. C.; Tomita, T.; Sohma, Y.*; Kanai, M.*
Near-Infrared Photoactivatable Oxygenation Catalysts of Amyloid Peptide
Chem 2018, 4, 807-820 (DOI: 10.1016/j.chempr.2018.02.008).
[108]
Wakaki, T.; Togo, T.; Yoshidome, D.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C-H Bond Activation
ACS Catal. 2018, 8, 3123-3128 (DOI: 10.1021/acscatal.8b00440).
Wakaki, T.; Togo, T.; Yoshidome, D.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Synthesis of Diaryl Ketones from Aldehydes and (Hetero)Aryl Halides via C-H Bond Activation
ACS Catal. 2018, 8, 3123-3128 (DOI: 10.1021/acscatal.8b00440).
[107]
Shirai, T.; Kanai, M.*; Kuninobu, Y.*
2-Position-Selective C-H Perfluoroalkylation of Quinoline Derivatives
Org. Lett. 2018, 20, 1593-1596 (DOI: 10.1021/acs.orglett.8b00339).
Shirai, T.; Kanai, M.*; Kuninobu, Y.*
2-Position-Selective C-H Perfluoroalkylation of Quinoline Derivatives
Org. Lett. 2018, 20, 1593-1596 (DOI: 10.1021/acs.orglett.8b00339).
2017
[106]
Kuninobu, Y.*; Yamamoto, M.; Nishi, M.; Yamamoto, T.; Matsuki, T.; Murai, M.*; Takai, K.*
Rhenium-Catalyzed ortho-Alkylation of Phenols
Org. Synth. 2017, 94, 280-291 (DOI: 10.15227/orgsyn.094.0280).
Kuninobu, Y.*; Yamamoto, M.; Nishi, M.; Yamamoto, T.; Matsuki, T.; Murai, M.*; Takai, K.*
Rhenium-Catalyzed ortho-Alkylation of Phenols
Org. Synth. 2017, 94, 280-291 (DOI: 10.15227/orgsyn.094.0280).
[105]
Li, H.-L.; Kanai, M.*; Kuninobu, Y.*
Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives
Org. Lett. 2017, 19, 5944-5947 (DOI: 10.1021/acs.orglett.7b02936).
[Synfacts 2018, 14, 81.]
Li, H.-L.; Kanai, M.*; Kuninobu, Y.*
Iridium/Bipyridine-Catalyzed ortho-Selective C-H Borylation of Phenol and Aniline Derivatives
Org. Lett. 2017, 19, 5944-5947 (DOI: 10.1021/acs.orglett.7b02936).
[Synfacts 2018, 14, 81.]
[104]
Yoshigoe, Y.; Kuninobu, Y.*
Iron-Catalyzed ortho-Selective C-H Borylation of 2-Phenylpyridines and Their Analogs
Org. Lett. 2017, 19, 3450-3453 (DOI: 10.1021/acs.orglett.7b01423).
[Synfacts 2017, 13, 976.]
Yoshigoe, Y.; Kuninobu, Y.*
Iron-Catalyzed ortho-Selective C-H Borylation of 2-Phenylpyridines and Their Analogs
Org. Lett. 2017, 19, 3450-3453 (DOI: 10.1021/acs.orglett.7b01423).
[Synfacts 2017, 13, 976.]
[103]
Wang, Z.; Kanai, M.; Kuninobu, Y.*
Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents
Org. Lett. 2017, 19, 2398-2401 (DOI: 10.1021/acs.orglett.7b00923).
Wang, Z.; Kanai, M.; Kuninobu, Y.*
Iron-Catalyzed Acyloxyalkylation of Styrenes Using Hypervalent Iodine Reagents
Org. Lett. 2017, 19, 2398-2401 (DOI: 10.1021/acs.orglett.7b00923).
[102]
Li, H.-L.; Kuninobu, Y.*; Kanai, M.*
Lewis Acid-Base Interaction-Controlled ortho-Selective C-H Borylation of Aryl Sulfides
Angew. Chem. Int. Ed. 2017, 56, 1495-1499 (DOI: 10.1002/anie.201610041).
[Synfacts 2017, 13, 297] [Web of Science: Highly-Cited Paper]
Li, H.-L.; Kuninobu, Y.*; Kanai, M.*
Lewis Acid-Base Interaction-Controlled ortho-Selective C-H Borylation of Aryl Sulfides
Angew. Chem. Int. Ed. 2017, 56, 1495-1499 (DOI: 10.1002/anie.201610041).
[Synfacts 2017, 13, 297] [Web of Science: Highly-Cited Paper]
2016
[101]
Kuninobu, Y.*
Development of Novel C-H Bond Transformations Directed Towards Organic Functional Molecules
J. Synth. Org. Chem. Jpn. 2016, 74, 1058-1068.
[Accounts]
Kuninobu, Y.*
Development of Novel C-H Bond Transformations Directed Towards Organic Functional Molecules
J. Synth. Org. Chem. Jpn. 2016, 74, 1058-1068.
[Accounts]
[100]
Kuninobu, Y.*; Nishi, M.; Kanai, M.*
5-Position-selective C-H Trifluoromethylation of 8-Aminoquinoline Derivatives
Org. Biomol. Chem. 2016, 14, 8092-8100 (DOI: 10.1039/C6OB01325B).
Kuninobu, Y.*; Nishi, M.; Kanai, M.*
5-Position-selective C-H Trifluoromethylation of 8-Aminoquinoline Derivatives
Org. Biomol. Chem. 2016, 14, 8092-8100 (DOI: 10.1039/C6OB01325B).
[99]
Wang, Z.; Sueki, S.; Kanai, M.; Kuninobu, Y.*
Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C-H Bond of Aromatic and Heteroaromatic Imidates
Org. Lett. 2016, 18, 2459-2462 (DOI: 10.1021/acs.orglett.6b01012).
Wang, Z.; Sueki, S.; Kanai, M.; Kuninobu, Y.*
Rhenium-Catalyzed Synthesis of 1,3-Diiminoisoindolines via Insertion of Carbodiimides into a C-H Bond of Aromatic and Heteroaromatic Imidates
Org. Lett. 2016, 18, 2459-2462 (DOI: 10.1021/acs.orglett.6b01012).
[98]
Nagase, M.; Kuninobu, Y.*; Kanai, M.*
4-Position-Selective C-H Perfluoroalkylation and Perfluoroarylation of Six-Membered Heteroaromatic Compounds
J. Am. Chem. Soc. 2016, 138, 6103-6106 (DOI: 10.1021/jacs.6b01753).
Nagase, M.; Kuninobu, Y.*; Kanai, M.*
4-Position-Selective C-H Perfluoroalkylation and Perfluoroarylation of Six-Membered Heteroaromatic Compounds
J. Am. Chem. Soc. 2016, 138, 6103-6106 (DOI: 10.1021/jacs.6b01753).
[97]
Murai, M.*; Takeuchi, Y.; Yamauchi, K.; Kuninobu, Y.; Takai, K.*
Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters
Chem. Eur. J. 2016, 22, 6048-6058 (DOI: 10.1002/chem.201504718).
[Hot Paper]
Murai, M.*; Takeuchi, Y.; Yamauchi, K.; Kuninobu, Y.; Takai, K.*
Rhodium-Catalyzed Synthesis of Chiral Spiro-9-silabifluorenes by Dehydrogenative Silylation: Mechanistic Insights into the Construction of Tetraorganosilicon Stereocenters
Chem. Eur. J. 2016, 22, 6048-6058 (DOI: 10.1002/chem.201504718).
[Hot Paper]
[96]
Sueki, S.; Wang, Z.; Kuninobu, Y.*
Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C-H Bond Activation
Org. Lett. 2016, 18, 304-307 (DOI: 10.1021/acs.orglett.5b03474).
[Synfacts 2016, 12, 407] [ [Web of Science: Highly-Cited Paper]
Sueki, S.; Wang, Z.; Kuninobu, Y.*
Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C-H Bond Activation
Org. Lett. 2016, 18, 304-307 (DOI: 10.1021/acs.orglett.5b03474).
[Synfacts 2016, 12, 407] [ [Web of Science: Highly-Cited Paper]
2015
[95]
Kuninobu, Y.*; Sueki, S.
C-H Bond Transformations Leading to the Synthesis of Organic Functional Materials
Synthesis 2015, 47, 3823-3845 (DOI: 10.1055/s-0035-1560346).
[Review] [Cover]
Kuninobu, Y.*; Sueki, S.
C-H Bond Transformations Leading to the Synthesis of Organic Functional Materials
Synthesis 2015, 47, 3823-3845 (DOI: 10.1055/s-0035-1560346).
[Review] [Cover]
[94]
Kuninobu, Y.*; Ida, H.; Nishi, M.; Kanai, M.*
A meta-selective C-H borylation directed by a secondary interaction between ligand and substrate
Nature Chem. 2015, 7, 712-717 (DOI: 10.1038/nchem.2322).
[Nature Chem. news & views: Ackermann, L.; Li, J. Nature Chem. 2015, 7, 686-687] [Web of Science Highly-Cited Paper]
Kuninobu, Y.*; Ida, H.; Nishi, M.; Kanai, M.*
A meta-selective C-H borylation directed by a secondary interaction between ligand and substrate
Nature Chem. 2015, 7, 712-717 (DOI: 10.1038/nchem.2322).
[Nature Chem. news & views: Ackermann, L.; Li, J. Nature Chem. 2015, 7, 686-687] [Web of Science Highly-Cited Paper]
[93]
Kuninobu, Y.*; Nagase, M.; Kanai, M.*
Benzylic C(sp3)-H Perfluoroalkylation of Six-Membered Heteroaromatic Compounds
Angew. Chem. Int. Ed. 2015, 54, 10263-10266 (DOI: 10.1002/anie.201505335).
Kuninobu, Y.*; Nagase, M.; Kanai, M.*
Benzylic C(sp3)-H Perfluoroalkylation of Six-Membered Heteroaromatic Compounds
Angew. Chem. Int. Ed. 2015, 54, 10263-10266 (DOI: 10.1002/anie.201505335).
[92]
Murai, M.*; Takeshima, H.; Morita, H.; Kuninobu, Y.; Takai, K.*
Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)-H Bonds
J. Org. Chem. 2015, 80, 5407-5414 (DOI: 10.1021/acs.joc.5b00920).
[Featured Article]
Murai, M.*; Takeshima, H.; Morita, H.; Kuninobu, Y.; Takai, K.*
Acceleration Effects of Phosphine Ligands on the Rhodium-Catalyzed Dehydrogenative Silylation and Germylation of Unactivated C(sp3)-H Bonds
J. Org. Chem. 2015, 80, 5407-5414 (DOI: 10.1021/acs.joc.5b00920).
[Featured Article]
[91]
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C-H Bond Activation
J. Am. Chem. Soc. 2015, 137, 6140-6143 (DOI: 10.1021/jacs.5b02435).
[Web of Science: Highly-Cited Paper]
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Oxirane-Opening Reaction with Arenes via C-H Bond Activation
J. Am. Chem. Soc. 2015, 137, 6140-6143 (DOI: 10.1021/jacs.5b02435).
[Web of Science: Highly-Cited Paper]
[90]
Saito, K.; Chikkade, P. K.; Kanai, M.*; Kuninobu, Y.*
Palladium-Catalyzed Construction of Heteroatom-Containing π-Conjugated Systems by Intramolecular Oxidative C-H/C-H Coupling Reaction
Chem. Eur. J. 2015, 21, 8365-8368 (DOI: 10.1002/chem.201501116).
Saito, K.; Chikkade, P. K.; Kanai, M.*; Kuninobu, Y.*
Palladium-Catalyzed Construction of Heteroatom-Containing π-Conjugated Systems by Intramolecular Oxidative C-H/C-H Coupling Reaction
Chem. Eur. J. 2015, 21, 8365-8368 (DOI: 10.1002/chem.201501116).
[89]
Sueki, S.; Kuninobu, Y.*
Rhodium-Catalyzed Synthesis of Multi-Substituted Silylindenes from Aryl Alkynes and Hydrosilanes via C-H Bond Activation
Chem. Commun. 2015, 51, 7685-7688 (DOI: 10.1039/c5cc01569c).
Sueki, S.; Kuninobu, Y.*
Rhodium-Catalyzed Synthesis of Multi-Substituted Silylindenes from Aryl Alkynes and Hydrosilanes via C-H Bond Activation
Chem. Commun. 2015, 51, 7685-7688 (DOI: 10.1039/c5cc01569c).
[88]
Chikkade, P. K.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates
Chem. Sci. 2015, 6, 3195-3200 (DOI: 10.1039/C5SC00238A).
[Twenty-five most downloaded articles between April and June, 2015]
Chikkade, P. K.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Intermolecular C(sp3)-H Bond Functionalization Towards the Synthesis of Tertiary Carbamates
Chem. Sci. 2015, 6, 3195-3200 (DOI: 10.1039/C5SC00238A).
[Twenty-five most downloaded articles between April and June, 2015]
[87]
Wakaki, T.; Kanai, M.*; Kuninobu, Y.*
Iridium-Catalyzed ortho-Selective C-H Silylation of Aromatic Compounds Directed toward the Synthesis of -Conjugated Molecules with Lewis Acid-Base Interaction
Org. Lett. 2015, 17, 1758-1761 (DOI: 10.1021/acs.orglett.5b00529).
Wakaki, T.; Kanai, M.*; Kuninobu, Y.*
Iridium-Catalyzed ortho-Selective C-H Silylation of Aromatic Compounds Directed toward the Synthesis of -Conjugated Molecules with Lewis Acid-Base Interaction
Org. Lett. 2015, 17, 1758-1761 (DOI: 10.1021/acs.orglett.5b00529).
[86]
Murai, M.*; Omura, T.; Kuninobu, Y.; Takai, K.*
Rhenium-Catalysed Dehydrogenative Borylation of Primary and Secondary C(sp3)-H Bonds Adjacent to a Nitrogen Atom
Chem. Commun. 2015, 51, 4583-4586 (DOI: 10.1039/C4CC09508A).
Murai, M.*; Omura, T.; Kuninobu, Y.; Takai, K.*
Rhenium-Catalysed Dehydrogenative Borylation of Primary and Secondary C(sp3)-H Bonds Adjacent to a Nitrogen Atom
Chem. Commun. 2015, 51, 4583-4586 (DOI: 10.1039/C4CC09508A).
2014
[85]
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Copper-Mediated Direct C(sp3)-H and C(sp2)-H Acetoxylation
Org. Lett. 2014, 16, 4790-4793 (DOI: 10.1021/ol5022542).
[Synfacts 2014, 10, 1310]
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Copper-Mediated Direct C(sp3)-H and C(sp2)-H Acetoxylation
Org. Lett. 2014, 16, 4790-4793 (DOI: 10.1021/ol5022542).
[Synfacts 2014, 10, 1310]
[84]
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Molybdenum-Mediated Desurfurization of Thiols and Disulfides
Synlett 2014, 25, 1869-1872 (DOI: 10.1055/s-0034-1378315).
Wang, Z.; Kuninobu, Y.*; Kanai, M.*
Molybdenum-Mediated Desurfurization of Thiols and Disulfides
Synlett 2014, 25, 1869-1872 (DOI: 10.1055/s-0034-1378315).
[83]
Matsuo, Y.*, Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura, E.*
Fiedel-Crafts Functionalization of the Cyclopentadienyl Ligand of Buckymetallocenes
Dalton Trans. 2014, 43, 7407-7412 (DOI: 10.1039/c3dt52002a).
Matsuo, Y.*, Kuninobu, Y.; Ito, S.; Sawamura, M.; Nakamura, E.*
Fiedel-Crafts Functionalization of the Cyclopentadienyl Ligand of Buckymetallocenes
Dalton Trans. 2014, 43, 7407-7412 (DOI: 10.1039/c3dt52002a).
[82]
Kanyiva, K. S.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Direct C–H Silylation and Germanylation of Benzamides and Carboxyamides
Org. Lett. 2014, 16, 1968-1971 (DOI: 10.1021/ol500519y).
Kanyiva, K. S.; Kuninobu, Y.*; Kanai, M.*
Palladium-Catalyzed Direct C–H Silylation and Germanylation of Benzamides and Carboxyamides
Org. Lett. 2014, 16, 1968-1971 (DOI: 10.1021/ol500519y).
[81]
Takemura, N.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Benzylic C(sp3)-H Alkoxylation of Heterocyclic Compounds
Org. Biomol. Chem. 2014, 12, 2528-2532 (DOI: 10.1039/C4OB00215F).
Takemura, N.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Benzylic C(sp3)-H Alkoxylation of Heterocyclic Compounds
Org. Biomol. Chem. 2014, 12, 2528-2532 (DOI: 10.1039/C4OB00215F).
[80]
Nishida, T.; Fukazawa, A.; Yamaguchi, E.; Oshima, H.; Yamaguchi, S.; Kanai, M.*; Kuninobu, Y.*
Synthesis of Pyridine N-Oxide-BF2CF3 Complexes and Their Fluorescence Properties
Chem. Asian J. 2014, 9, 1026-1030 (DOI: 10.1002/asia.201301688).
Nishida, T.; Fukazawa, A.; Yamaguchi, E.; Oshima, H.; Yamaguchi, S.; Kanai, M.*; Kuninobu, Y.*
Synthesis of Pyridine N-Oxide-BF2CF3 Complexes and Their Fluorescence Properties
Chem. Asian J. 2014, 9, 1026-1030 (DOI: 10.1002/asia.201301688).
[79]
Wang, Z.; Ni, J.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Intramolecular C(sp3)-H and C(sp2)-H Amidation by Oxidative Cyclization
Angew. Chem. Int. Ed. 2014, 53, 3496-3499 (DOI: 10.1002/anie.201311105).
[Synfacts 2014, 10, 570]
Wang, Z.; Ni, J.; Kuninobu, Y.*; Kanai, M.*
Copper-Catalyzed Intramolecular C(sp3)-H and C(sp2)-H Amidation by Oxidative Cyclization
Angew. Chem. Int. Ed. 2014, 53, 3496-3499 (DOI: 10.1002/anie.201311105).
[Synfacts 2014, 10, 570]
[78]
Xiao, Q.; Meng, X.; Kanai, M.*; Kuninobu, Y.*
Palladium-Catalyzed C-H Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents
Angew. Chem. Int. Ed. 2014, 53, 3168-3172 (DOI: 10.1002/anie.201310293).
Xiao, Q.; Meng, X.; Kanai, M.*; Kuninobu, Y.*
Palladium-Catalyzed C-H Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents
Angew. Chem. Int. Ed. 2014, 53, 3168-3172 (DOI: 10.1002/anie.201310293).
[77]
Nishida, T.; Ida, H.; Kuninobu, Y.*; Kanai, M.*
Regioselective Trifluoromethylation of N-Heteroaromatic Compounds using Trifluoromethyldifluoroborane Activator
Nat. Commun. 2014, 5, 3387 (DOI: 10.1038/ncomms4387).
[Nature Communications Chemistry Selections]
Nishida, T.; Ida, H.; Kuninobu, Y.*; Kanai, M.*
Regioselective Trifluoromethylation of N-Heteroaromatic Compounds using Trifluoromethyldifluoroborane Activator
Nat. Commun. 2014, 5, 3387 (DOI: 10.1038/ncomms4387).
[Nature Communications Chemistry Selections]
